Oh of course, I forgot to mention that in the rush...So here's a short manual.
First of all, I built the latest versions of the extension libraries for 64 bit. The easiest way to do this is to download the source packages from the developers' sites and use CMake for Makefile (resp. .vsxproj) generation.
libjpeg however is a bit off at that, since it has no CMakeFileList.txt. Instead you have to - watch out, it's really sophistical... - rename the file makevcxproj.v10 and adjust the file extension, as it is simply a disguised Visual Studio 2010 project. Additionally, the file jconfig.h should be overwritten with the content of jconfig.vc, at least it's recommended by the installation guide.
All of the other libraries should build just fine when you have a very basic knowledge on how to work with CMake (the GUI makes it kind of snap, actually).
You should then replace the files in your SFML2.0/extlibs folder with those you just created (and of course rename them accordingly) and then have your VS2010 solution generated by CMake once again for the SFML2.0 build. You need to do this two times: One time with "Build shared" enabled, and one time without, so that all of the needed binaries are created.
Then just load up the respective solution and build the "BUILD-ALL" project. If everything was adjusted correctly, you should, after a few seconds - or minutes, depending on your processor - be the proud owner of a freshly baked SFML2.0 64 bit build.
I hope this short instruction was helpful
regards,
Debilo