It's not about Xinerama alone. I've read a bit about this recently as well and as far as I know now, the Pi doesn't have any hardware acceleration in/through X11 (probably the reason for the crashes/issues). Instead, you'd have to get an OpenGL (ES) context using other means (don't remember specifics right now), which would cause the hardware accelerated context to run "on top" of the X desktop. This would have to be implemented into SFML first. There's no way to use SFML's window/graphics modules right now out of the box.