But are there other similar functions in SFML that begin with "To"?
"To" functions usually apply to small utility classes that can be converted to another type, and SFML has very few of them. As far as I remember, there are "To" functions only in sf::String and sf::Utf.
Or maybe a future sf::Time::ToStdDuration() interacting with Chrono?
If I add such a conversion in the future, it will most likely be implicit. Since the type std::duration holds the semantic ("it's a duration"), unlike sf::Int32 which doesn't make it clear that you'll get milliseconds, there's no need have an explicit conversion function.
std::duration<...> d = clock.GetElapsedTime();
...looks good enough to me.
Same for the other way round:
sf::Sleep(std::seconds(1));