Xcode 4.6.2 (the latest version) runs on OS X 10.7, and it'll default to the same things that Xcode 4.6.2 on 10.8 does.
Also, I'm not sure that the "default" settings make a huge difference, seeing as people will most likely use the Xcode templates SFML provides, so then it's SFML's template's defaults that make a difference, not the Xcode defaults.
Also, 10.7 supports C++11 & libc++ just fine. There's a reason you can set your target to 10.7 when building a C++11 application in Xcode. it's not problematic at all. You don't have to worry about missing symbols.
And finally, I'd also suggest noting on the downloads page that the Clang builds are linking to libc++ and support C++11. Otherwise, it's not obvious they link to libc++ and support C++11 (and thus look like they should support OS X 10.5, which is why I was puzzled in the first place).