So yesterday this worked find up until today.
I followed the tutorial for setting up VS2010, although it left out sfml-main.lib and sfml-main-d.lib.
Everything is setup as it should be with everything pointed to the right file paths and all the includes are right.
It also runs fine in release mode, but if I change the debug mode sfml-main to the release version it will still fail while in debug mode, but release mode works fine, and they are pointing to the same file.
I am sure I will need o provide more information, I will check back every 30 minutes or so while I am in class.